Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
443.97 0.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
505.08 1.9

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
506.08 0.3
547.22 0.2
569.0 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
606.35 0.3
623.86 0.2
633.98 0.2
647.08 0.6

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
648.76 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
649.15 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
649.98 0.2
667.1 13.1

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
667.74 0.4
668.17 1.4
768.83 0.2
789.47 0.2
808.95 2.3

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
809.31 1.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
811.15 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
828.27 0.2
829.19 18.6

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
830.02 1.0
830.29 0.6
869.13 0.3
870.29 2.1

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
871.21 0.2
911.42 0.2
912.36 0.2
934.33 0.3

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
951.89 0.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
954.53 0.2
971.18 0.6
971.92 0.2
972.22 0.2
1012.21 0.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1013.93 0.4

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1014.31 0.9

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1015.33 0.2
1032.23 26.3

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1033.32 2.4
1034.2 0.2
1054.22 0.2
1074.07 0.2
1103.94 0.3
1133.66 0.2
1134.23 0.3
1152.16 0.2
1174.2 7.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1175.23 0.7
1175.78 0.2
1176.21 1.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1176.83 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1177.39 0.4
1191.98 0.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1194.23 50.8

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1195.23 8.9
1199.39 0.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1218.34 0.2
1234.21 0.9
1235.3 3.5

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1235.98 0.2
1277.19 0.7
1277.5 0.2
1318.88 0.2
1319.42 0.7
1320.4 0.3
1337.18 0.8
1355.19 0.3
1355.45 0.2
1356.29 0.4
1378.25 0.3
1379.29 3.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1379.89 0.4

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1380.31 0.5
1396.32 0.2
1397.28 61.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1398.2 9.9
1398.52 3.6
1399.28 0.2
1439.3 0.3
1440.36 0.8
1455.27 0.2
1456.78 0.2
1469.57 0.2
1478.4 0.2
1499.38 1.7
1499.68 0.6
1500.31 0.3
1517.16 0.7
1517.72 0.4
1528.16 0.3
1528.44 0.2
1529.4 0.2
1534.48 0.2
1541.33 0.5
1559.17 1.2

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1559.43 0.8

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1560.34 165.1
1561.35 15.8

There are 3 similar spectra:

Id Structure Score

1.00

6670

0.98

0.98

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1558.51
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

Report errors in this entry

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