Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
443.95 0.6

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
444.16 0.3

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
444.7 0.2
445.02 0.2
605.78 1.3

Annotations:

CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
606.24 1.4

Annotations:

CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
607.2 0.3
647.15 0.7

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
647.45 0.2

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
648.16 0.2
649.06 0.6

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
667.1 2.9

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
680.13 0.4
708.23 0.4
718.89 0.3
726.15 0.3
809.11 19.2

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
810.24 0.7
812.1 0.2
827.11 0.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
827.45 0.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
829.21 3.6

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
830.21 0.9
852.04 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
870.27 1.8

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
870.52 0.8

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
870.9 0.2
871.25 0.5
922.94 0.3
942.17 0.2
951.16 0.4
954.38 0.4
971.21 7.1

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
971.88 0.2
972.33 1.6
989.32 0.2

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
996.44 0.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1012.11 0.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1012.4 1.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1013.09 0.3
1013.39 0.2
1014.08 0.9

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1032.18 20.9

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1033.28 2.3
1045.49 0.4
1134.07 0.5
1145.62 0.2
1146.26 0.2
1152.14 0.3
1153.28 0.2
1155.93 0.2

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
1156.26 0.5
1158.47 0.2
1174.23 16.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1175.29 2.8
1176.29 0.3

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1176.64 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1192.11 0.3

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1192.58 0.4

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1194.25 41.9

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1195.03 1.7
1195.37 3.7
1217.01 0.5

Annotations:

ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1217.43 0.2

Annotations:

ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1235.19 0.6

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1235.46 0.6

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1235.65 0.3

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
1236.28 0.8
1246.19 0.2
1265.08 0.3
1277.19 0.2
1277.46 0.2
1289.39 0.2
1338.25 0.5
1343.41 0.2
1355.43 0.2
1356.35 0.2
1361.43 0.5
1362.46 0.2
1378.37 0.4
1379.38 3.4

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
1381.34 0.2
1397.28 50.6

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1398.3 11.2
1439.29 0.4
1439.96 0.3
1440.35 0.8
1499.56 0.8
1500.2 0.3
1501.53 0.3
1512.31 0.3
1517.35 0.9
1517.75 0.4
1528.2 0.4
1540.87 0.3
1558.95 0.4
1559.47 1.2

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1560.33 180.3
1561.4 6.3
1561.9 0.4

There are 1 similar spectra:

Id Structure Score

6669

0.98

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1558.51
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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