Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
168.01 0.3

Annotations:

^{1,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_5--4b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-2H,0,redEnd
169.89 0.4
170.7 0.1
186.3 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
197.99 0.1
202.01 0.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
212.13 0.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
219.91 0.1

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
259.21 0.1

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
271.97 0.2
290.09 30.5

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
291.03 3.5

Annotations:

^{1,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
291.54 0.1

Annotations:

^{1,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
292.07 0.5

Annotations:

^{0,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_4--4b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
299.99 0.2
302.04 0.1
311.96 0.1
328.09 0.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
333.19 0.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd
333.55 0.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd
338.53 0.2
360.93 0.1

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
362.66 0.1

Annotations:

^{0,2}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_2(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd
386.23 0.1
386.62 0.1
388.97 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
400.27 0.2
405.07 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd
414.18 0.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd ^{1,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
416.21 0.1

Annotations:

^{1,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_5--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
432.89 0.1
444.12 0.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
444.39 0.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
449.18 0.9
449.67 0.2
456.18 0.1
459.06 0.1
460.66 0.1
461.31 0.1
462.05 0.3

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
462.26 0.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
463.11 0.1
468.64 0.1

Annotations:

^{0,2}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_2(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-2H,0,redEnd
470.36 0.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
474.96 0.1
475.43 0.2
475.76 0.3
478.06 0.1
488.07 0.1
497.78 0.1
498.02 0.1
504.1 0.1

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
505.66 0.1
506.61 0.1
507.66 0.2

Annotations:

^{0,2}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_2(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-2H,0,redEnd
514.2 0.1
515.83 0.1
516.35 0.2
517.14 0.1
520.44 0.3
521.02 0.1
529.22 0.1
529.68 0.1
534.12 0.4

Annotations:

^{0,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
569.89 0.1
571.02 0.1
631.18 0.4
647.78 0.1
648.28 0.1
649.14 10.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
650.03 1.2
650.29 1.0
651.23 0.1
651.7 0.1
667.15 4.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
668.24 0.6
668.97 0.1
695.03 0.1
777.62 0.1
790.14 0.1
806.83 0.1
807.96 0.1
810.18 0.1
810.81 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
811.27 1.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
812.23 0.1

Annotations:

^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
813.19 0.1
813.41 0.1
824.89 0.2
825.33 0.2
827.03 0.4
827.61 0.1
827.99 0.1
829.21 160.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
830.23 52.1

Annotations:

^{1,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
831.25 11.9
880.58 0.1
885.34 0.1
900.42 0.1
922.34 0.1

There are 3 similar spectra:

Id Structure Score

1.00

6683

0.99

0.99

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1119.34
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • 78 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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