Structure

    redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd

Ion Mobility-Tandem Mass Spectrometry of Mucin-type O-Glycans: from Healthy Sputum

The MS/MS data was generated after TIMS separation and retention time refers to CCS values in Ų

GlyTouCan Accession Number: Loading...

Peak Intensity
62.2561 332.0
94.7701 114.0
208.1593 173.0
295.0519 619.0
299.1256 471.0
348.1223 639.0
364.1161 1204.0

Annotations:

B a1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
365.1289 486.0

Annotations:

Y^{2,4}X_{GlcNAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
389.1537 932.0

Annotations:

ZZ redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
389.1672 327.0

Annotations:

ZZ redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
401.4972 287.0
407.178 411.0

Annotations:

YZ redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
425.2174 233.0

Annotations:

YY redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
425.5963 129.0
425.8329 134.0
468.0275 392.0

Annotations:

^{2,5}A_{GalNAc}Y a1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
496.9622 669.0

Annotations:

^{0,3}X_{GlcNAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd ^{0,3}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_3)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,4}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_4)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y^{0,3}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd Y^{1,4}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_1_4$MONO,Und,-H,0,redEnd
497.1828 317.0

Annotations:

^{0,3}X_{GlcNAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd ^{0,3}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_3)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,4}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_4)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y^{0,3}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd Y^{1,4}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_1_4$MONO,Und,-H,0,redEnd
527.2262 302.0

Annotations:

^{2,4}X_{GlcNAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd ^{0,4}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,3}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_3)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y^{0,4}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Y^{1,3}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd Y^{2,4}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
545.23 233.0
568.1717 407.0
569.2074 1318.0

Annotations:

Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
569.2288 2992.0

Annotations:

Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
569.2805 337.0

Annotations:

Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
569.5128 119.0

Annotations:

Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
570.2279 639.0
571.2043 183.0
571.6735 233.0
605.0348 124.0
749.272 193.0

Annotations:

redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
749.2935 238.0

Annotations:

redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
750.2782 173.0

There are 8 similar spectra:

Id Structure Score

3496

0.76

0.76

0.76

5428

0.74

7884

0.73

7239

0.72

5178

0.72

7953

0.67

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 748.29
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Sputum

Mass Spec

N/A

MIRAGE Structural data

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