Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd

Ion Mobility-Tandem Mass Spectrometry of Mucin-type O-Glycans: from Healthy Sputum

The MS/MS data was generated after TIMS separation and retention time refers to CCS values in Ų

GlyTouCan Accession Number: Loading...

Peak Intensity
81.255 238.0
110.2097 278.0
162.5412 486.0
240.9144 669.0

Annotations:

BY b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
241.0046 530.0

Annotations:

BY b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
285.0496 481.0

Annotations:

^{1,3}A_{Gal} b1D-Gal,p/#acleavage_1_3(--3?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
313.4629 367.0
315.0342 1467.0

Annotations:

^{1,4}A_{Gal} b1D-Gal,p/#acleavage_1_4(--3?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd ^{3,5}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_3_5--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{1,4}X_{Fuc} b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_1_4$MONO,Und,-H,0,redEnd
343.066 287.0

Annotations:

B^{0,4}X_{Fuc} b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd ^{0,2}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
366.0508 317.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
389.1548 352.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
426.0792 496.0

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
443.7701 342.0
444.0022 238.0

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
444.0638 580.0

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
444.0787 3286.0

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
444.1013 1858.0

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
444.2455 238.0

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
445.0973 565.0
445.376 278.0
457.0175 223.0
478.5397 238.0
504.0908 396.0

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,2}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
504.1049 659.0

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,2}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
504.1194 342.0

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,2}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
534.1214 307.0

Annotations:

^{0,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,3}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
535.1163 287.0
564.0581 327.0

Annotations:

C^{0,4}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd
564.112 932.0

Annotations:

C^{0,4}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd
567.6181 278.0
569.2168 377.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S/#lcleavage)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S/#lcleavage)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
572.1355 401.0
590.1361 486.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
591.1742 302.0
601.182 327.0
620.1661 496.0
625.1977 322.0

Annotations:

Z^{1,4}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S/#lcleavage)--2a1L-Fuc,p/#xcleavage_1_4$MONO,Und,-H,0,redEnd
649.1728 1571.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
667.1905 11142.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
667.2532 392.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
667.3005 342.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
667.5859 327.0
667.6792 228.0
667.9392 422.0
668.2016 1933.0
668.828 233.0
669.1408 203.0
669.6365 248.0
710.1793 273.0

Annotations:

^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
772.2237 278.0
787.2074 317.0
811.2259 595.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
826.4723 327.0
826.9283 332.0
829.2014 416.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
829.238 14062.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
829.2687 4381.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
829.313 585.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
829.3551 624.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
830.2327 2443.0
830.254 2393.0
830.287 704.0
830.7065 332.0
831.0333 352.0
831.1199 233.0
831.3825 372.0
834.605 292.0
975.3034 1729.0

Annotations:

redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
975.3561 263.0

Annotations:

redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p(--3?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
976.2892 620.0

There are 4 similar spectra:

Id Structure Score

7900

0.88

7901

0.85

6655

0.82

6654

0.72

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 974.31
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Sputum

Mass Spec

N/A

MIRAGE Structural data

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