Structure

    redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
262.96 8.7
280.92 8.7

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p$MONO,Und,-H,0,redEnd
346.0 11.1

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
348.02 4.4

Annotations:

ZZ redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.02 28.8

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
382.03 71.8

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd C b1D-Gal,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
383.04 5.5
384.04 6.7

Annotations:

YY redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
388.95 3.2
407.13 10.3
424.09 56.7

Annotations:

^{0,4}A_{Gal} b1D-Gal,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
424.53 9.0
425.12 12.8
445.11 3.3
454.03 4.9
466.03 4.1
467.02 3.5
479.03 6.3
490.13 16.5
491.1 3.2
492.92 3.0
501.02 3.0
503.1 3.0
508.1 322.4

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
508.5 15.5
509.06 55.6
509.54 3.5
524.44 4.2
526.11 68.3

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
527.12 31.6

Annotations:

^{0,4}X_{Gal} redEnd--??1D-GalNAc,p--3b1D-Gal,p/#xcleavage_0_4--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
528.06 7.9
545.15 5.1
546.12 6.9
551.12 19.4

Annotations:

ZZ redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
569.15 65.5

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
569.77 5.4
570.17 16.9
587.19 107.1

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
588.15 29.0
599.02 5.1
622.19 3.0
641.15 15.6
664.07 6.2
664.26 5.1
665.25 8.2
669.16 4.7
671.16 17.6
682.19 3.0
687.2 4.5
688.22 3.0
689.23 74.2

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p--3b1D-Gal,p/#xcleavage_2_4--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
690.17 13.5
707.17 7.1
708.19 3.9
712.18 38.6
713.2 12.0
724.11 4.0
729.19 124.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
730.14 48.4

Annotations:

^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
731.17 47.9

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
732.18 13.7
746.59 4.9
749.2 257.3

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
750.16 61.1
750.85 4.4
751.16 3.6
751.36 3.9
754.08 6.3
754.26 5.0
755.11 6.0
772.22 211.4

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
773.2 70.7
790.24 67.0

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
791.22 28.5
802.22 50.6
803.25 11.8
832.2 9.7
833.29 4.3
833.83 5.5
843.13 4.5
844.24 163.7
845.22 44.0
846.12 3.2
850.27 12.0
851.19 6.5
854.4 5.7
856.28 2.9
871.1 3.8
874.16 5.9
889.07 3.4
890.27 3.9
891.13 5.3
892.26 408.9
893.25 129.5
893.71 3.0
908.2 3.0
909.1 4.7
910.26 149.6
911.25 58.5
916.09 5.7

There are 9 similar spectra:

Id Structure Score

8010

0.76

5733

0.73

4869

0.72

0.72

8011

0.70

7735

0.63

3132

0.53

5206

0.53

0.50

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 951.37
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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