Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p@360)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
329.01 2.4
346.05 8.5
347.07 1.7
364.02 11.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3b1D-GlcNAc,p@360$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
365.01 1.8
381.89 2.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3b1D-GlcNAc,p@360$MONO,Und,-H,0,redEnd C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
389.06 36.3

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
389.35 8.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.07 6.8
407.07 26.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
407.48 2.2
408.2 2.7
423.05 4.7
424.04 11.3

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3b1D-GlcNAc,p@360$MONO,Und,-H,0,redEnd
425.04 4.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
434.0 1.8
434.96 1.7
438.5 2.2
459.94 2.2
466.27 4.4
475.87 2.2
479.27 6.0
491.29 2.9
504.16 2.6
508.03 5.9
509.07 12.7
521.11 9.7
522.57 2.5
527.16 46.9

Annotations:

^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p--3b1D-GlcNAc,p@360$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
528.24 5.6
533.17 5.2
545.12 3.2
546.34 5.5
549.14 2.9
550.2 3.6
551.18 6.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p/#zcleavage@360)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
569.14 443.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p/#ycleavage@360)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p/#zcleavage@360)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p@360)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
570.09 93.4
570.91 4.7
587.16 93.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p/#ycleavage@360)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p@360)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
588.1 17.2
592.13 6.8
602.41 2.2
610.21 4.4
627.1 3.1
631.52 3.0
661.19 20.6
664.19 1.9
671.2 2.0
673.52 3.6
676.23 2.1
690.28 4.4
690.54 2.2
707.14 1.9
710.53 2.1
712.21 23.0
713.1 3.8
724.31 4.5
729.13 5.9
730.2 23.0

Annotations:

^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p@360)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
730.99 4.7
731.24 9.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p/#zcleavage@360)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
732.18 3.2
743.19 2.3
743.77 2.4
748.37 9.7
749.21 23.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p/#ycleavage@360)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
750.25 5.2
754.34 4.7
755.59 3.7
757.08 2.2
772.22 215.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p@360)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
773.23 43.2
790.22 78.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3b1D-GlcNAc,p@360)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
790.7 3.3
791.16 18.2
827.17 1.9
828.18 3.0
832.12 3.8
844.22 21.0
845.13 2.5
846.1 6.7
852.23 6.3
862.17 3.0
871.24 6.6
876.62 2.6
887.25 4.1
890.05 5.0
892.26 52.0
893.22 16.9
907.03 2.4
908.37 2.9
909.18 4.0
910.29 35.9
911.22 13.9
911.8 3.8
916.18 2.3
917.52 5.7
918.54 5.0
925.22 2.5

There are 15 similar spectra:

Id Structure Score

0.99

3761

0.95

4870

0.95

0.95

5795

0.94

4267

0.85

3760

0.80

7736

0.74

7898

0.74

5585

0.73

3132

0.66

0.65

5584

0.61

4266

0.55

8010

0.50

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 951.37
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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