Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
275.97 13.4
290.01 79.2

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.99 10.2
306.01 49.2

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
307.04 6.4
322.92 7.5
367.11 5.7
369.19 5.8
371.11 5.5
396.09 5.6
397.13 6.3
412.11 10.4
413.13 6.8
414.19 5.7
424.12 7.1

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
439.14 5.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
440.11 5.2
441.14 6.9
451.04 7.0
452.14 6.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
453.17 5.3
456.19 9.6
467.15 11.1

Annotations:

Y^{0,2}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
468.17 13.9

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
470.11 16.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
471.11 13.0
482.14 7.5
494.36 5.3
495.19 8.8
497.16 10.2
509.21 5.4

Annotations:

Z^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
510.17 7.1
511.23 5.4
512.17 8.5

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
513.13 18.9
514.12 7.0
524.21 10.8
526.13 6.8
527.07 6.2

Annotations:

Y^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
541.06 6.2
544.26 5.1
553.24 7.6
558.2 7.1
559.24 5.8
565.2 5.6
567.12 6.1
568.11 6.8
571.18 7.2
572.11 7.7
573.07 6.2
574.17 12.4
575.27 5.6
581.11 9.7
582.24 8.4
584.25 5.4
585.11 14.4
586.08 8.0
591.22 7.7
591.46 7.7
592.14 8.6
593.15 6.5
600.2 6.1
608.12 26.0
609.22 29.5
609.56 13.2
610.2 41.4
611.25 43.3
612.17 25.0
614.11 6.1
624.22 10.3
625.23 8.4
626.2 29.9
627.22 24.2
628.23 72.0
629.22 77.0
630.22 44.9
636.22 18.2
637.17 28.8
638.19 25.5
641.62 6.0
642.27 40.3
643.26 53.2
644.24 68.6
749.26 20.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
878.25 18.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
962.26 9.2
1020.26 8.8
1022.32 23.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
1023.3 8.4
1026.29 26.0
1027.25 10.0
1038.32 10.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1039.38 7.0
1040.32 241.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1041.29 130.9
1042.32 48.3
1043.3 7.8
1056.29 147.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1057.29 64.5
1058.33 14.4

There are 3 similar spectra:

Id Structure Score

3523

0.87

5218

0.78

6823

0.60

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1346.48
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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