Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
210.83 8.2
238.96 20.0
302.98 6.2
306.01 169.2

Annotations:

B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
307.0 20.7
308.04 7.3
310.97 6.5
324.01 5.8

Annotations:

C a2D-NeuGc,p/#ccleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
341.19 7.5
385.19 8.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
408.05 6.9
411.96 7.2
425.14 7.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
427.16 7.8
438.12 9.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
439.14 8.5
457.25 10.6
470.29 9.4
471.16 8.9
502.18 9.3
510.17 7.7
511.27 9.1
516.16 7.4
516.67 18.9
519.92 9.6
522.11 6.6
525.04 8.5
535.07 7.0
536.14 6.5
541.15 6.0
547.88 7.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
551.21 22.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
552.22 7.1
556.15 10.7
568.19 5.9
569.15 135.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.2 31.0
572.13 10.5
573.09 6.9
582.11 14.0
583.09 13.0
584.2 10.9
586.23 11.1
587.07 15.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
587.24 11.1
588.17 6.1
591.09 13.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
595.1 23.2
600.12 17.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
603.36 12.7
606.79 8.9
608.99 12.6
610.2 9.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
611.0 13.3
611.67 7.4
613.12 313.3

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
613.67 7.3
614.2 52.7
615.02 10.7
617.73 55.1
619.3 13.1
620.99 11.5
636.29 8.8
638.25 12.9
639.17 70.7
640.26 12.2
641.27 8.6
647.76 12.3
650.11 7.4
655.16 8.3
657.12 15.6
658.18 20.9
659.18 22.1
660.01 6.3
665.25 11.8
665.69 7.2
666.19 30.3
667.23 15.7
668.15 8.7
670.0 14.6
671.27 11.9

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
672.17 26.9
673.09 7.1

Annotations:

^{2,4}A_{Gal} ?1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
790.28 150.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.24 53.9
791.64 8.0
792.28 28.6
794.17 8.8
860.26 7.5
876.31 10.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1003.24 10.3
1097.33 209.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1098.32 88.9
1099.34 60.3
1100.28 6.2
1165.26 34.3
1165.5 8.8
1166.07 16.1
1166.32 13.5
1311.3 7.1

There are 1 similar spectra:

Id Structure Score

8119

0.68

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1403.50
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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