Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
276.0 23.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
287.99 14.8

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
306.03 959.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
307.01 116.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
308.0 20.3
315.1 11.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
324.03 41.5

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd C a2D-NeuGc,p/#ccleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
376.06 11.1
384.11 129.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
385.12 20.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
396.05 16.3

Annotations:

^{0,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_3--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
405.11 452.1

Annotations:

B b1D-Gal,p/#bcleavage--?HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.1 87.6

Annotations:

B b1D-Gal,p/#bcleavage--?HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
407.08 11.8

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
417.55 17.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
426.04 10.4

Annotations:

^{0,4}A_{NeuGc} a2D-NeuGc,p/#acleavage_0_4--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
487.13 15.3

Annotations:

^{0,2}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_2(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
489.6 23.9

Annotations:

^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
494.11 15.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
498.62 94.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
499.12 39.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
499.57 16.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
509.1 11.2
521.15 28.5
525.12 56.3

Annotations:

^{1,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
526.11 17.2
529.15 12.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
537.19 10.6
543.13 50.2

Annotations:

^{0,2}A_{NeuGc} a2D-NeuGc,p/#acleavage_0_2--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
544.11 14.5

Annotations:

^{0,2}A_{NeuGc} a2D-NeuGc,p/#acleavage_0_2--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
551.13 18.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
558.11 18.3
559.05 11.4
567.15 21.9

Annotations:

^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
569.16 72.6

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#ycleavage)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.13 18.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#ycleavage)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
574.17 38.0
574.64 19.8
582.18 15.2
583.14 353.5
583.66 163.0
584.14 74.4
584.58 12.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
584.93 12.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
591.14 32.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
591.64 17.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
592.11 13.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
595.1 32.6
596.09 13.4
597.17 37.8
600.16 76.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
600.64 40.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
601.16 24.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
611.11 33.0
612.15 12.3
613.14 896.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
614.12 223.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
615.12 58.2
631.13 41.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
632.09 16.6

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
637.11 13.6
638.16 18.1
639.17 29.4
640.15 16.4
641.18 11.1
647.66 12.1
654.71 22.6

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
655.17 20.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
656.14 25.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
657.14 27.3
658.13 19.9
659.08 17.1
663.17 12.5
663.69 34.5
664.21 26.8
665.17 33.6
666.18 38.4
667.2 25.8
670.65 19.6
671.16 69.7
671.62 17.2
672.16 35.4
673.18 26.9

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
754.23 15.9
772.22 17.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
790.26 286.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.25 89.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p--??1HexNAc,p)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
792.23 27.4
800.22 30.9
860.26 50.6
861.24 20.8

Annotations:

^{2,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
922.24 15.2
950.26 17.5

Annotations:

^{1,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
954.26 32.4
955.29 13.4
962.25 21.6
980.25 304.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
981.23 130.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#zcleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
982.26 39.3
998.27 11.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--?HexNAc,p/#ycleavage)--6a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd

There are 1 similar spectra:

Id Structure Score

8065

0.68

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1403.50
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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