Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.05 6.2
305.97 216.6

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
306.98 25.1
320.43 5.3
325.11 6.2
340.1 6.0
364.07 7.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
366.2 6.3
407.13 22.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
424.1 10.0

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
435.26 6.7
436.13 10.6
439.03 6.5
442.1 7.0
456.0 15.8
526.14 8.3
539.32 9.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
544.2 10.5
545.08 6.5
569.15 28.6

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
569.39 5.3
570.14 14.8
580.04 7.3
581.01 12.4
582.18 8.3
587.12 7.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
592.17 8.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
597.05 10.7
600.21 18.9
603.57 10.4
607.46 9.5
609.37 5.4
618.08 13.1
627.18 10.1
635.99 9.3
640.93 7.0
657.08 12.0
660.76 9.6
671.47 9.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
672.65 11.2
673.14 31.9
684.45 6.7
689.17 21.9

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
692.68 13.3
693.24 11.4
693.58 11.8
694.28 11.8
694.95 21.4
710.29 6.1
711.35 8.4
720.48 13.5
721.06 18.8
721.25 12.0
728.84 7.1
731.29 5.4

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
738.53 18.7
739.3 23.7
741.2 11.7
742.28 6.7
745.31 19.5
748.21 5.8
752.41 6.5
753.72 36.5
758.42 6.2
790.08 9.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
835.33 7.4
847.58 11.4
876.27 23.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
876.56 9.7
877.27 15.8
877.55 10.0
919.28 8.0
952.31 55.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.32 16.2
953.92 5.9
954.26 7.8
968.22 5.7
997.27 8.2
1028.79 8.8
1029.7 6.0
1039.21 5.8
1097.42 6.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1116.42 9.7
1141.33 7.2
1158.43 12.5
1159.32 7.6
1165.34 15.1
1166.52 10.8
1200.23 5.4
1201.11 5.9
1215.4 13.4
1241.32 17.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1242.32 6.6
1259.36 661.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1260.38 417.1
1261.32 139.0
1261.66 15.7
1317.49 6.4
1479.54 6.5
1531.47 5.3

There are 1 similar spectra:

Id Structure Score

8125

0.63

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1565.55
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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