Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
252.83 3.2
266.41 5.4
304.18 2.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
305.97 147.8

Annotations:

BY ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
306.4 7.1

Annotations:

BY ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
307.07 11.6

Annotations:

BY ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
389.09 18.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
395.43 3.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd ^{1,4}A_{Gal}Y ?1D-Gal,p/#acleavage_1_4--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
402.03 4.9
425.01 3.9

Annotations:

^{0,2}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_2(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd ^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
430.09 2.8
479.15 4.2
494.2 6.5

Annotations:

^{1,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_4--3b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
494.7 2.9

Annotations:

^{1,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_4--3b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
495.1 5.4

Annotations:

^{1,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_4--3b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
520.14 3.5
525.08 16.6

Annotations:

^{3,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
526.19 5.7

Annotations:

^{3,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd ^{2,5}A_{NeuGc} a2D-NeuGc,p/#acleavage_2_5--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
533.24 3.6

Annotations:

^{0,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
543.08 2.8

Annotations:

^{0,2}A_{NeuGc} a2D-NeuGc,p/#acleavage_0_2--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
551.0 8.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
567.07 3.5
569.17 129.9

Annotations:

^{0,2}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_2(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
570.07 26.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
570.73 3.8
571.15 5.7
579.68 3.8
582.18 6.1
587.19 6.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.16 5.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
592.12 3.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
593.16 6.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
594.99 9.2
595.35 4.8

Annotations:

^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
613.09 205.3

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
613.57 7.0

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
614.1 56.6

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
615.05 11.5
615.26 4.6
616.54 4.6
620.19 2.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
628.69 5.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
636.61 7.5
637.2 2.7
639.25 5.2
651.1 3.6

Annotations:

^{0,2}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_2(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
651.45 5.4
655.63 6.6
658.09 7.9
663.6 3.1
664.19 12.2
664.55 5.8
665.09 2.8
672.81 3.1

Annotations:

^{1,3}A_{Gal} ?1D-Gal,p/#acleavage_1_3--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal} ?1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
682.1 6.7
683.68 6.5
689.27 3.5

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
702.13 9.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
702.7 4.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd ^{1,4}A_{Gal} ?1D-Gal,p/#acleavage_1_4--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
703.17 7.1

Annotations:

^{1,4}A_{Gal} ?1D-Gal,p/#acleavage_1_4--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
706.62 3.2
713.69 4.0

Annotations:

^{0,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
716.44 4.3

Annotations:

^{2,5}A_{Gal} ?1D-Gal,p/#acleavage_2_5--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
720.42 3.2
722.12 3.4
730.18 5.4
735.17 6.1
738.63 2.9
743.74 7.0

Annotations:

^{0,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
746.82 3.2

Annotations:

^{1,5}A_{Gal} ?1D-Gal,p/#acleavage_1_5--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
751.13 8.1
752.13 4.6
752.7 4.3
790.19 10.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
876.23 4.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
892.22 4.0
910.27 2.8
946.12 6.4
952.25 195.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.21 75.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.63 6.6
954.22 19.9
1022.3 5.7
1023.21 5.0
1040.4 4.2
1135.27 3.0
1157.29 5.5

Annotations:

^{0,2}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_2(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1165.32 33.7
1166.29 16.1
1167.45 5.3
1183.33 4.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1239.09 3.0
1241.28 9.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
1242.28 4.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
1259.31 171.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1260.36 135.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1261.37 32.3
1368.45 3.5
1382.31 5.5
1472.28 7.0

There are 2 similar spectra:

Id Structure Score

8078

0.67

8079

0.63

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1565.55
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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