Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
363.11 2.8
389.07 2.6

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
405.11 88.7

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.04 22.0
407.09 22.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
423.12 7.4

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
502.13 5.0
503.02 2.1
507.04 2.9
512.95 2.2
543.8 2.7
544.16 20.2
545.1 9.8
562.15 3.2
564.67 4.0
567.58 3.3

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
569.17 4.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.2 3.4
574.21 2.3
587.18 47.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.13 9.7
588.72 2.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
589.18 6.4
592.16 16.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
597.69 39.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
598.25 12.1
598.66 5.0
608.19 119.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
609.16 31.1
610.29 7.2
611.2 3.6
615.05 2.6
630.57 3.7
645.23 4.6
645.68 2.2
650.12 2.3
655.51 3.1
665.2 2.5
666.23 7.5
666.72 11.4
667.22 4.3
668.21 7.3

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
690.22 6.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
690.66 4.3
699.24 28.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
699.7 12.8
700.22 4.6
710.25 4.0
711.8 3.5
720.04 8.7
724.2 6.4
725.23 2.1
727.58 2.7
747.7 5.1
747.98 2.7
752.85 2.3
753.95 2.2
754.26 2.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
756.34 2.8
757.44 2.9
769.82 3.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
770.85 3.1
771.42 4.3
813.24 12.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
814.31 10.3
815.19 3.3
831.24 9.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
831.43 6.0
951.33 4.2
975.38 14.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
976.3 5.4
993.31 206.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
994.29 90.1
995.31 22.2
995.74 2.4
1016.36 48.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1017.36 17.7
1018.33 6.4
1088.32 2.5
1130.32 16.2
1130.83 2.4
1131.45 4.4
1136.37 2.7
1160.29 2.8

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1178.35 28.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1179.23 7.0
1179.47 4.6
1180.3 5.6
1196.4 212.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1197.39 82.9
1197.81 5.0
1198.31 21.4
1198.53 11.5
1199.32 7.8
1333.45 9.7
1334.43 6.0
1363.39 3.1
1381.45 13.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1382.62 2.7
1383.48 4.4

There are 4 similar spectra:

Id Structure Score

8081

0.91

8084

0.90

8082

0.79

8126

0.71

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1601.63
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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