Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.03 10.3
389.12 4.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
405.11 83.5

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.51 4.7
406.06 16.5
407.12 18.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
408.12 5.3
423.12 16.0

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
502.1 5.4
544.16 29.7
545.2 5.2
556.01 2.7
567.19 17.8

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
569.22 3.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
574.17 7.3
585.56 2.8

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
587.18 16.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.18 3.0
592.21 30.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
593.2 10.7
594.14 3.2
597.77 4.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
598.21 3.5
599.05 2.5
608.2 128.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
609.11 36.3
610.2 16.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
628.09 2.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
628.37 3.0
650.16 3.6
668.19 17.9

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
669.12 3.9
682.3 4.1
690.27 7.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
699.22 40.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
699.7 21.0
700.2 7.9
710.24 17.0
724.29 2.6
747.98 3.1
754.22 5.5

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
756.26 7.3
757.3 6.2
759.29 4.2
759.87 4.3
761.55 4.0
764.08 2.4
764.94 5.5
765.29 4.5
765.97 3.1
770.05 6.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
770.72 9.6
771.21 9.1
771.74 2.4
832.33 2.4
871.23 10.5
872.22 5.5
933.36 6.6
934.37 2.9
956.27 5.8
956.56 2.5
957.26 3.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
975.31 67.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
976.27 31.8
977.4 4.2
993.33 292.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
994.3 114.2
994.89 3.4
995.33 31.3
995.88 5.8
998.37 2.8
999.38 2.4
1016.35 180.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1017.34 65.0
1018.38 13.5
1034.36 34.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1035.35 15.0
1070.23 3.2
1088.32 7.3
1101.54 4.1
1118.39 2.7
1130.37 37.6
1131.4 14.3
1132.37 2.8
1136.44 2.9
1137.4 2.4
1142.43 4.7
1160.39 13.6

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1161.41 3.4
1178.39 19.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1179.43 9.5
1196.4 176.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1197.4 99.7
1197.9 6.3
1198.39 35.9
1333.45 2.7
1381.45 3.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1382.49 4.8
1399.51 2.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1401.64 3.6

There are 4 similar spectra:

Id Structure Score

8084

0.96

8080

0.91

8082

0.74

8126

0.52

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1601.63
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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