Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
405.09 110.1

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.09 21.4
407.11 3.7
423.07 12.3

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
551.15 2.9

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
553.2 9.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
554.21 4.6
568.14 4.3
571.28 7.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
572.17 4.9
608.16 74.1

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
609.13 23.3
610.02 4.2
654.58 3.0
670.7 13.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
671.22 14.8
671.68 4.5
683.16 3.6
711.22 4.0
720.34 3.6
721.35 2.9
724.7 2.8
725.18 3.5
733.22 26.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
734.29 4.2
740.17 3.1
745.2 4.2
754.25 3.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
763.24 6.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
771.17 4.3
771.78 2.8
772.25 58.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
772.71 40.6
773.21 21.7
785.26 3.7
786.06 3.0
790.23 26.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.28 6.6
792.25 5.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd
792.71 8.5
793.17 4.7

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
794.42 3.0
802.31 2.8
811.18 4.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
812.5 3.4
813.08 5.1
814.1 5.0

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
821.14 3.6
823.8 2.8
829.53 3.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
830.17 8.2
830.55 2.9
838.26 6.7
843.35 3.4
843.84 15.4
844.32 5.6
915.39 5.5
916.22 5.2
927.33 5.8
928.23 4.9
936.21 12.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
936.71 3.2
957.3 9.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
958.29 4.3
959.26 6.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1017.27 11.9

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1018.35 13.6
1079.39 5.0
1102.27 4.0
1120.31 3.8
1121.37 9.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1139.38 153.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1139.89 6.3
1140.36 68.0
1140.95 3.2
1141.38 23.0
1144.38 3.2
1162.39 85.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1163.37 55.2
1163.83 5.8
1164.37 8.4
1180.4 59.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1181.38 33.0
1182.4 7.3
1276.42 6.7
1277.28 4.8
1282.56 5.4
1283.43 3.5
1324.45 9.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1325.55 8.2
1342.46 296.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1343.44 165.8
1343.91 6.2
1344.46 58.7
1344.88 4.0
1451.43 3.8
1509.45 13.2
1510.78 3.0
1527.54 6.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1528.66 3.1

There are 3 similar spectra:

Id Structure Score

8096

0.98

8130

0.71

8131

0.56

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1747.69
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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