Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
389.13 4.0
405.08 183.1

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.53 8.7
406.08 33.1
423.07 32.9

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
551.14 5.7

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
553.16 22.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
554.15 9.6
567.16 32.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
568.14 4.8
569.18 6.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
571.17 10.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
572.23 4.9
589.74 3.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
590.58 4.6
608.18 157.8

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
608.68 5.1
609.14 31.6
610.16 5.9
661.7 4.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
670.71 22.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
671.2 13.0
673.17 3.8
682.21 9.5
709.39 4.9
724.65 6.6
733.25 44.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
734.25 15.7
743.23 5.3
755.98 3.8
756.27 5.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
763.28 4.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
772.23 167.8

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
772.71 78.4
773.27 46.1
774.19 9.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
774.44 5.1
790.24 73.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.19 23.9
791.99 5.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd
793.93 4.2
811.24 18.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
812.06 4.4
829.05 4.8

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
830.34 3.7
843.2 5.7
843.74 23.1
844.33 7.0
885.29 4.3
915.28 14.4
916.29 5.5
918.34 4.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
927.32 13.1
928.25 8.9
936.32 19.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
937.32 8.0
939.35 4.8
957.32 20.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
958.3 7.1
959.27 12.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
959.56 4.0
975.21 3.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
993.28 6.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1017.33 31.6

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1018.36 9.9
1044.23 3.8
1079.28 7.4
1080.4 5.5
1084.45 6.1
1102.39 4.9
1120.47 5.3
1121.4 11.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1122.28 6.0
1139.38 303.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1140.35 154.5
1141.36 43.7
1144.38 5.4
1145.39 5.0
1162.39 217.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1163.36 115.6
1163.84 6.6
1164.39 27.1
1180.42 109.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1181.41 56.2
1182.38 15.2
1276.42 6.6
1282.46 12.8
1283.38 6.3
1324.45 22.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1325.47 9.7
1342.44 488.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1343.45 341.8
1344.44 107.0
1345.38 6.6
1366.51 4.6
1509.47 5.9
1510.52 5.6
1527.39 10.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1527.64 8.3
1528.71 5.0

There are 3 similar spectra:

Id Structure Score

8095

0.98

8130

0.67

8131

0.53

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1747.69
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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