Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
405.09 70.9

Annotations:

B ?1HexNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.07 11.5
423.05 20.6

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
551.13 3.9

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
553.14 15.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
554.14 5.9
571.15 10.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
608.18 117.2

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
609.16 38.9
610.14 10.1
622.55 3.1
626.18 4.7

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
670.7 2.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
690.25 6.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd
691.23 3.1
733.24 24.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
734.24 12.2
738.27 3.5

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
770.21 15.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
772.21 14.7

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
772.72 15.9
773.23 7.8
774.21 3.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
790.21 11.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.17 4.6
811.23 51.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
812.23 15.3
843.7 2.8
855.71 3.2
870.2 3.4
873.74 32.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
874.28 37.7
874.79 4.4
885.3 5.4
886.21 3.2
903.76 3.2
910.8 3.2
914.16 6.3
922.57 3.3
923.1 3.5
932.36 6.8
933.6 4.6
934.6 4.0
936.25 19.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
937.37 6.9
938.28 2.8
939.21 3.5
940.17 4.3
940.53 3.2
945.22 6.9
993.29 20.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
994.26 6.6
1017.31 11.0

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1018.4 4.7
1100.37 3.6
1102.48 7.6
1103.5 3.3

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1118.17 3.0
1118.49 4.3
1119.38 6.2
1120.31 4.2
1130.25 6.9
1131.41 3.6
1139.39 52.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1140.37 28.5
1141.45 10.7
1160.42 15.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
1161.37 6.5
1162.39 126.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1163.35 70.6
1163.81 6.5
1164.54 10.7
1165.32 3.0
1180.41 54.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1181.38 28.8
1182.32 7.7
1282.45 10.0
1283.42 8.8
1324.42 18.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1325.23 3.1
1325.58 4.0
1342.44 250.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1343.45 138.6
1344.47 40.7
1345.37 10.5
1365.46 23.3
1366.48 7.3
1367.55 3.3
1383.5 7.7
1384.42 8.1
1384.73 2.8
1479.48 4.5
1485.53 4.5
1486.49 6.1
1527.66 2.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1528.51 5.9
1545.53 135.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1546.53 110.9
1547.5 49.5
1548.48 5.4

There are 3 similar spectra:

Id Structure Score

1.00

8108

0.98

0.98

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1950.77
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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