Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
405.11 132.7

Annotations:

B ?1HexNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.14 21.2
407.03 5.7
423.12 41.6

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
424.07 5.6
553.16 33.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
554.13 13.1
567.19 10.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
571.18 9.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
572.11 11.1
608.18 196.2

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
609.15 57.3
610.13 10.0
690.22 7.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd
691.23 8.1
733.2 29.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
734.21 11.8
751.73 4.7
756.21 6.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
770.24 28.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
771.15 5.4
772.24 37.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
772.74 10.6
773.28 12.7
774.23 5.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
790.25 26.1
791.2 8.4
811.27 111.5

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
812.24 34.6
813.22 10.6
843.75 4.7
873.76 58.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
874.27 49.7
874.74 18.7
885.31 5.8
915.28 7.8
927.27 10.6
928.35 5.4
936.31 30.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
936.7 4.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
937.3 16.3
938.27 5.2
939.29 8.6
940.23 6.4
945.27 9.3
993.31 55.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
994.34 22.1
1017.32 21.7

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1018.26 7.4
1079.43 6.2
1102.3 8.5
1118.36 17.1
1119.27 6.7
1120.39 9.1
1121.4 8.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1126.36 4.9
1130.39 23.7
1131.29 8.0
1132.37 5.0
1139.37 165.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1140.36 90.4
1141.34 32.5
1142.42 8.5
1144.41 9.2
1160.36 23.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
1161.3 13.4
1162.4 249.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1163.42 128.2
1164.39 29.9
1165.37 8.2
1180.41 108.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1181.41 46.5
1182.33 12.0
1282.45 12.7
1283.39 7.6
1324.48 20.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1342.46 365.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1343.45 238.7
1344.43 72.5
1345.41 14.1
1365.46 48.9
1366.38 24.5
1366.61 13.2
1367.52 9.9
1383.48 33.9
1384.48 16.9
1385.51 5.8
1485.53 14.1
1486.47 15.2
1487.48 6.1
1509.48 5.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1527.54 12.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1528.55 16.3
1529.52 8.1
1545.54 240.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1546.53 152.7
1547.54 74.2
1548.42 13.2
1548.63 10.3
1730.72 4.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd

There are 3 similar spectra:

Id Structure Score

1.00

8107

0.98

0.98

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1950.77
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

Report errors in this entry

UniCarb-DR Creative Commons License

Supported by SIB ExPASy  |  JST / NBDCDICP