Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
241.16 0.3

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
241.73 0.0
259.23 0.1

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
266.01 0.1
298.98 0.1
300.98 0.3

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
301.58 0.0
305.13 0.1
314.78 0.2

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
315.1 0.3

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
315.67 0.0
343.06 0.1
361.17 0.2

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
361.7 0.0
366.21 0.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
389.31 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
389.84 0.0
404.1 0.1
407.13 0.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
407.37 0.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.29 0.1
414.0 0.1
426.05 0.1
443.08 0.1
444.08 17.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
445.13 2.1
445.79 0.1
462.05 0.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
464.12 0.1
464.47 0.1
485.38 0.2
485.93 0.0
486.93 0.1
504.01 0.2

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
504.44 0.2

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
505.08 0.2
505.64 0.0
528.11 0.2
528.69 0.0
548.44 0.2
549.02 0.0
563.85 0.2
568.94 0.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
569.37 0.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
584.9 0.1
589.35 0.4
589.93 0.0
590.35 0.2
590.91 0.0
606.6 0.1
607.24 0.1
618.55 0.1
624.95 0.1
647.17 0.1
648.09 0.0
649.18 0.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
649.49 0.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
650.07 0.6
650.57 0.1
667.17 34.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
668.2 8.5
668.9 0.0
669.22 0.1
670.01 0.1
699.89 0.2
700.45 0.0
708.91 0.1
709.66 0.1
710.23 0.4

Annotations:

^{2,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
710.72 0.1
721.19 0.1
727.71 0.2
728.28 0.0
732.7 0.1
739.03 0.1
739.36 0.1
766.78 0.2
767.34 0.0
769.32 0.4
769.95 0.0
770.29 0.2
777.0 0.2
777.55 0.0
778.98 0.1
783.04 0.1
784.61 0.1
785.11 0.1
787.14 0.5
787.37 0.4
788.27 0.1
789.06 0.1
789.4 0.1
789.9 0.1
790.45 0.0
811.29 0.1
811.82 0.0
828.84 0.1

Annotations:

redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
829.42 0.1

Annotations:

redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
830.37 0.2
830.94 0.0

There are 21 similar spectra:

Id Structure Score

1.00

6652

1.00

1.00

5783

1.00

1.00

3123

0.99

0.97

3122

0.91

3499

0.91

6651

0.91

0.91

5392

0.90

0.90

5568

0.90

0.89

6689

0.89

0.89

6682

0.88

0.88

6727

0.74

5784

0.60

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 828.25
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • 78 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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