Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
202.1 2.2
253.96 2.1
272.0 4.2

Annotations:

BZ b1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
290.01 309.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
290.55 12.2
291.02 44.6
292.0 7.1

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
295.04 2.5
299.99 2.7
307.99 5.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd CY b1D-Gal,p/#ccleavage--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
366.09 2.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
380.09 5.4

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
383.18 2.2
384.03 2.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
389.02 2.2
398.07 3.0
400.09 6.7
401.02 4.9

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
407.11 47.2
408.07 6.0
425.14 5.3
435.96 3.3

Annotations:

Z^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
455.14 2.2
456.1 2.2
457.08 3.0
458.07 2.0
464.07 3.0
465.01 10.2
466.02 2.1
468.05 2.5
469.19 5.0
482.03 2.2
482.62 71.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
483.09 40.4
483.54 9.5
484.05 2.7
484.97 3.5
494.05 5.3
495.04 5.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
509.03 2.6
510.13 2.3
512.11 5.2

Annotations:

^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
513.09 4.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
519.1 9.7
527.2 3.6
528.11 3.5
529.11 4.8
530.12 5.8
531.17 3.4
533.02 2.6
537.14 38.6
537.55 2.7
538.12 12.0
539.04 3.6
539.28 3.3
547.11 2.5
547.58 2.0
549.01 4.5
553.08 3.0
554.02 3.8
555.08 4.0
557.01 2.7
563.13 4.4
565.15 4.6
566.12 6.4
567.18 7.1
568.17 2.9
571.13 3.6
579.21 5.1
580.09 5.1
580.37 3.8
581.14 580.0

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.13 144.4
583.11 24.0
584.09 20.3
585.07 7.0
591.09 4.8
592.08 4.3
593.09 9.0
595.24 2.1
597.11 10.2
598.09 71.5
598.51 3.7
599.08 25.5

Annotations:

C b1D-Gal,p/#ccleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
657.27 2.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
673.19 12.7
673.57 3.7
674.2 10.6
675.21 958.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
676.19 270.4
676.81 14.1
677.19 47.5
678.13 2.5
922.25 9.1
948.2 3.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
964.26 8.2
965.13 2.2
966.28 407.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
967.24 168.4
968.21 41.1

There are 2 similar spectra:

Id Structure Score

8051

0.99

6820

0.96

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1256.44
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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