Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
239.0 17.5
241.03 6.8
256.99 29.7
257.94 5.1
270.0 6.5
288.01 6.0
290.0 432.9

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd B a2D-NeuAc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
290.48 21.1
291.06 46.3
291.99 8.8

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
307.99 5.8

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd C a2D-NeuAc,p/#ccleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
324.98 12.3
334.93 6.9
340.05 5.7
341.04 8.0
357.11 13.7
368.04 10.3
370.07 16.8
371.12 17.5
380.07 14.4
384.04 4.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
386.05 18.8
398.09 5.0
407.15 24.9
439.09 4.7
453.16 6.0
454.07 7.4

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
466.06 6.0
468.16 9.1
469.08 12.4
473.6 9.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
474.07 6.4
478.1 6.2
481.25 8.9
482.1 11.4
482.62 119.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
483.09 73.8
483.59 29.4
484.11 7.9
484.98 5.3
493.14 5.6
494.07 6.8
495.1 7.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
499.17 124.8
500.14 28.9
508.06 5.2
509.12 7.3
510.08 8.0
511.13 5.2
512.16 8.3

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
513.18 5.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
519.08 11.9
527.05 8.6
530.15 11.0
531.06 9.1
532.08 5.0
537.13 92.4
538.12 19.6
539.2 7.6
540.05 6.2
549.13 4.7
550.03 5.3
556.75 8.5
563.12 10.3
564.14 10.1
565.08 27.3
566.17 17.3
566.98 8.2
568.18 5.1
579.12 16.2
580.08 17.6
581.13 630.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.08 181.9
583.08 65.3
584.13 20.1
585.11 9.3
590.99 7.2
592.15 21.3
593.14 27.2
594.15 5.3
597.16 50.7
598.09 112.8
599.1 44.4

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
600.11 8.5
657.18 13.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
673.15 30.9
674.2 9.7
675.21 1162.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
676.2 345.8
677.19 74.7
922.32 14.9
923.26 10.3
930.33 5.1
948.27 34.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
949.33 16.7
964.27 15.7
965.29 18.6
966.25 470.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
967.27 178.8
968.23 41.7

There are 2 similar spectra:

Id Structure Score

8050

0.99

6820

0.95

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1256.44
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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