Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
351.03 2.0
364.03 2.0
380.07 22.4
392.03 2.6
405.91 1.2
407.1 4.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
416.0 1.5
425.12 10.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
451.16 1.0
460.15 1.2
470.12 1.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
478.09 10.0
479.28 2.2
493.15 12.1
495.1 1.2
501.11 3.1
507.18 1.5
511.19 2.9
519.14 39.0
520.2 1.0
523.1 1.0
527.17 1.0

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
535.17 4.8
536.06 3.4
537.14 188.0
538.11 15.5
538.77 2.0
549.15 1.3
555.02 1.8
555.61 1.7
563.13 34.8
564.35 1.8
565.0 1.0
571.22 2.0
572.12 1.2
579.12 4.3
580.16 17.3
581.15 2029.2

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.14 128.8
582.64 8.0
583.12 10.0
584.13 1.0
587.19 86.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
587.68 1.0
588.28 2.6
652.94 1.2
655.27 1.4
657.21 4.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#xcleavage_0_2)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
657.67 1.1
658.19 2.8
673.27 1.4
675.09 1.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
726.18 1.9
728.21 5.4
740.14 1.3
760.03 1.0
770.24 11.4
771.22 2.4
793.18 1.7
800.25 7.0
801.05 1.7
812.32 3.2
816.48 1.0
818.27 2.4
834.31 25.4
835.03 1.3
835.42 2.8
842.26 3.2
860.27 107.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
861.26 18.3
862.23 1.9
869.88 1.1
876.28 8.9
877.31 31.2
878.28 4018.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
879.24 395.8
880.3 5.7
927.27 1.2
945.18 1.4
966.13 1.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
993.23 1.1
1013.2 1.1
1018.33 2.2
1043.43 1.0
1057.73 1.3
1073.2 1.4
1089.32 1.4
1090.26 1.4
1091.23 2.4
1107.33 16.6
1108.31 2.6
1109.35 88.1
1110.33 3.9
1124.35 4.5
1124.59 1.8
1125.37 571.0
1126.32 91.6
1127.13 2.8
1133.34 18.7
1134.13 1.3

There are 7 similar spectra:

Id Structure Score

4896

0.94

0.94

8041

0.89

7156

0.88

4897

0.88

0.88

7232

0.88

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1168.43
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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