Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
382.02 46.3

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CY b1D-Gal,p/#ccleavage--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
408.04 10.8
424.1 67.6

Annotations:

^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
425.1 8.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
479.11 6.5
490.11 14.5
494.11 18.8
508.1 221.0

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
509.13 47.5
512.15 5.7
526.12 99.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
527.12 23.8
536.1 37.2
537.12 8.4
549.16 9.2
551.19 13.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
552.16 7.7
554.1 6.6
567.14 5.9
569.15 42.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
570.14 5.7
587.2 125.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
588.17 27.2
622.15 7.6
641.17 7.2
671.16 14.6
682.2 9.7
689.18 31.2
690.2 6.9
712.2 19.0
713.21 13.8

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
729.2 67.8
730.23 40.7
731.21 54.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
732.21 16.0
749.23 166.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
750.22 43.4
754.25 29.5
755.18 10.4
772.25 262.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
773.23 57.3
781.13 7.6
790.26 443.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
791.23 149.2
802.22 20.7
803.25 9.7
830.24 16.9
832.32 6.9
844.28 96.4
845.25 29.4
856.31 7.6
858.24 51.7
859.24 14.5
874.28 9.6
892.29 153.0
893.29 50.4
900.23 44.8
901.24 13.3
910.27 52.6
911.27 21.6
916.31 5.7
930.2 19.8
934.29 231.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
935.29 75.4
948.27 132.0
949.25 43.4
951.31 7.5
952.3 2395.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
953.3 698.8
953.99 17.8
954.46 7.0
994.28 9.0
1004.32 7.1
1005.32 8.3
1022.3 76.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1023.33 33.0
1039.27 22.5
1040.33 22.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1041.31 30.8
1042.28 10.9
1045.31 15.4
1075.34 12.6
1076.3 11.0
1082.33 5.7
1105.38 10.8
1117.29 5.9
1123.37 8.8
1135.33 7.9
1147.33 7.1
1159.34 12.9
1165.35 298.1
1166.33 131.1
1177.38 6.0
1182.3 8.1
1183.38 613.1
1184.34 289.6
1184.99 6.4
1199.44 8.1
1207.38 83.5
1208.35 24.3

There are 11 similar spectra:

Id Structure Score

8048

0.98

3157

0.93

3779

0.91

4902

0.90

0.90

0.89

4279

0.88

5215

0.84

8049

0.77

5836

0.75

8047

0.61

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1242.47
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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