Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
364.08 0.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
389.09 14.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.17 7.1
407.13 4.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.05 1.2
411.03 1.3
424.09 4.0

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
437.11 1.1
451.16 1.5
460.18 1.2
479.1 8.4
479.3 2.5
491.12 1.1
509.1 4.9
527.09 7.3
527.48 0.1
528.02 8.4
533.34 1.5
545.12 2.2
546.05 0.8
562.14 1.5
568.18 1.0
569.1 149.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
569.88 2.5
570.22 11.8
570.5 0.1
574.19 1.3
587.18 27.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
587.71 0.0
588.08 3.1
593.33 0.7
610.27 0.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
611.27 1.9
666.87 2.5
683.11 3.0
744.35 1.1
749.34 2.5
772.26 44.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
773.19 9.4
773.7 1.4
784.31 0.9
784.63 0.0
790.17 24.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
790.44 0.7
791.27 7.5
791.6 0.1
820.09 1.6
830.36 3.1
835.12 1.1
836.34 1.6
846.46 1.9
888.19 2.3
891.35 1.6
892.4 7.3
910.42 2.8
910.72 0.0
911.82 1.3
934.13 1.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
934.5 0.7
948.28 1.9
952.26 103.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
953.29 23.1
953.49 6.9
953.78 0.1
954.97 2.6
978.15 1.9
986.16 3.8
998.21 3.6
1022.29 9.9
1023.24 1.2
1024.95 3.7
1039.3 0.9
1045.33 1.1
1051.15 3.0
1059.54 3.0
1061.22 0.7
1071.28 2.1
1075.31 2.0
1082.21 1.1
1083.33 2.2
1083.63 0.0
1114.84 1.3
1115.13 0.0
1127.5 0.8
1136.37 2.7
1142.39 0.7
1147.82 1.3
1157.44 4.0
1165.35 30.5
1166.27 19.9
1179.23 1.6
1183.34 34.8
1183.72 1.2
1184.28 3.6
1193.22 1.3
1198.36 2.6
1200.43 1.0
1207.3 1.9
1208.33 0.8
1243.51 6.0

Annotations:

redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd

There are 10 similar spectra:

Id Structure Score

8049

0.96

3157

0.69

4279

0.68

0.68

4902

0.63

0.63

8046

0.61

8048

0.61

3779

0.57

5215

0.51

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1242.47
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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