Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
364.08 6.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
389.08 42.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.1 3.9
407.11 64.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.04 6.4
424.02 9.4

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
425.11 13.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
479.15 8.1
506.19 4.0
509.11 8.5
521.2 3.1
527.12 25.9
528.15 2.5
532.22 3.0
533.06 3.7
551.16 19.5

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
552.18 2.5
569.17 504.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
570.17 66.3
570.74 9.2
587.18 87.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
588.15 13.3
592.22 8.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
593.14 2.3
610.14 10.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
611.18 3.4
628.3 3.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
712.2 9.0
718.23 2.6
730.24 9.6
731.28 7.7
748.21 4.7
754.26 6.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
755.28 2.5
772.24 148.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
773.25 37.6
782.19 3.0
790.25 125.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
790.68 7.7
791.23 42.5
800.27 3.7
816.26 23.8
817.17 5.7
830.25 6.8
834.33 3.1
842.28 6.8
859.14 4.9
860.15 2.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
878.45 4.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
879.31 6.1
892.24 17.7
893.29 6.2
910.29 17.9
911.27 4.5
931.15 2.8
931.36 2.3
934.23 32.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
934.66 3.3
935.29 6.6
948.22 8.5
949.26 2.4
950.25 2.9
951.38 3.9
952.29 549.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
953.27 168.5
953.87 3.5
985.38 2.9
994.31 5.0
1003.18 4.8
1004.29 8.8
1005.36 3.1
1019.36 2.8
1021.37 5.2
1022.29 25.2
1023.26 23.5
1045.3 13.4
1046.26 4.9
1046.78 3.0
1062.37 2.6
1063.27 3.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
1064.34 5.2
1075.29 3.3
1076.38 2.5
1081.31 4.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1082.37 13.9
1096.38 2.9
1129.27 2.4
1130.76 2.6
1135.49 2.8
1147.33 5.1
1161.37 2.5
1165.34 172.7
1166.35 63.8
1183.35 150.8
1184.34 82.4
1184.9 2.6
1189.17 3.9
1199.27 3.3
1199.55 2.3
1207.35 7.5

There are 11 similar spectra:

Id Structure Score

8047

0.96

3157

0.82

3779

0.80

4279

0.78

0.77

8046

0.77

8048

0.76

4902

0.76

0.76

5215

0.64

5836

0.55

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1242.47
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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