Structure

    redEnd--??1D-GalNAc,p--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
137.94 0.3
138.45 0.0
138.9 0.1

Annotations:

^{1,3}A_{Gal} b1D-Gal,p/#acleavage_1_3--3?1S$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal} b1D-Gal,p/#acleavage_2_4--3?1S$MONO,Und,-H,0,redEnd
139.43 0.0

Annotations:

^{1,3}A_{Gal} b1D-Gal,p/#acleavage_1_3--3?1S$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal} b1D-Gal,p/#acleavage_2_4--3?1S$MONO,Und,-H,0,redEnd
139.95 0.0
140.51 0.0
141.03 0.0
141.54 0.0
142.11 0.0
142.62 0.0
143.17 0.0
143.97 0.0
144.52 0.0
145.05 0.0
145.61 0.0
146.12 0.0
146.69 0.0
147.2 0.0
147.77 0.0
148.28 0.0
151.0 0.3
151.56 0.0
152.1 0.0
152.81 0.2
153.11 0.1
153.69 0.0
154.2 0.0
154.77 0.0
155.28 0.0
156.09 0.6
156.7 0.0
157.24 0.0
157.79 0.0
158.32 0.0
158.86 0.0
159.38 0.0
159.93 0.0
160.73 0.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
161.23 0.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
161.79 0.0
162.33 0.1
162.88 0.0
163.44 0.0
163.95 0.0
164.73 0.1
165.29 0.0
165.59 0.0
165.85 0.0
166.37 0.0
166.84 0.2
167.37 0.0
168.08 0.0
168.63 0.0

Annotations:

^{1,4}A_{Gal} b1D-Gal,p/#acleavage_1_4--3?1S$MONO,Und,-H,0,redEnd
169.05 0.1

Annotations:

^{1,4}A_{Gal} b1D-Gal,p/#acleavage_1_4--3?1S$MONO,Und,-H,0,redEnd
169.61 0.0
170.19 0.1
170.75 0.0
171.28 0.0
171.82 0.0
172.36 0.0
172.89 0.0
173.44 0.0
173.96 0.0
174.52 0.0
174.97 0.0
175.53 0.0
176.01 0.0
176.56 0.0
177.11 0.0
177.63 0.0
178.19 0.0
178.74 0.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
179.08 0.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
179.64 0.0
180.19 0.0
180.93 0.4
181.49 0.0
182.57 0.0

Annotations:

^{2,5}A_{Gal} b1D-Gal,p/#acleavage_2_5--3?1S$MONO,Und,-H,0,redEnd
183.04 0.1

Annotations:

^{2,5}A_{Gal} b1D-Gal,p/#acleavage_2_5--3?1S$MONO,Und,-H,0,redEnd
183.61 0.0
184.12 0.0
184.69 0.0
185.2 0.0
185.77 0.0
186.28 0.0
186.83 0.0
187.36 0.0
192.82 0.1
193.36 0.0
193.71 0.0
193.94 0.0
194.27 0.0
194.52 0.0
195.03 0.0
195.35 0.0
195.6 0.0
196.11 0.0
196.43 0.0
196.68 0.0
197.19 0.0
197.73 0.0
198.28 0.0
198.98 0.1

Annotations:

^{0,2}A_{Gal} b1D-Gal,p/#acleavage_0_2--3?1S$MONO,Und,-H,0,redEnd
199.55 0.0
200.11 0.0
200.63 0.0
201.19 0.0
201.71 0.0
202.27 0.0
202.78 0.0
203.34 0.0
204.17 0.4

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
204.99 0.1
205.5 0.0
205.88 0.0
206.09 0.0
206.59 0.0
206.96 0.0
207.17 0.0
207.67 0.0
208.04 0.0
208.25 0.0
208.75 0.0
209.13 0.0
209.32 0.0
212.14 0.1
212.71 0.0

Annotations:

^{1,5}A_{Gal} b1D-Gal,p/#acleavage_1_5--3?1S$MONO,Und,-H,0,redEnd
213.12 0.3

Annotations:

^{1,5}A_{Gal} b1D-Gal,p/#acleavage_1_5--3?1S$MONO,Und,-H,0,redEnd
213.88 0.1
214.45 0.0
214.98 0.0
215.53 0.0
216.05 0.0
216.61 0.0
217.13 0.0
217.69 0.0
218.21 0.0
221.95 0.4

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
222.52 0.0

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
223.05 0.2
223.61 0.0
224.25 0.1
224.82 0.0
225.39 0.0
225.89 0.0
226.47 0.0
226.96 0.0
227.55 0.0
228.06 0.0
228.62 0.0
240.97 13.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
242.17 0.5
242.91 0.1
243.11 0.1
243.64 0.0
244.22 0.0
244.72 0.0
245.29 0.0
245.94 0.1
246.52 0.0
247.03 0.0
247.37 0.0
247.6 0.0
248.11 0.0
248.45 0.0
248.93 0.0
249.47 0.0
250.03 0.0
250.55 0.0
251.11 0.0
251.62 0.0
252.19 0.0
252.89 0.0
253.44 0.0
253.97 0.0
254.53 0.0
255.05 0.0
255.61 0.0
256.13 0.0
256.69 0.0
257.2 0.0
259.11 0.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
259.66 0.0
260.12 0.1
260.84 0.1
261.39 0.0
261.94 0.0

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
262.46 0.0

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
263.02 0.0
263.54 0.0
264.1 0.0
264.62 0.0

Annotations:

^{2,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_5--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
265.18 0.0

Annotations:

^{2,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_5--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
265.8 0.2
266.36 0.0
266.88 0.0
267.44 0.0
267.96 0.0
268.52 0.0
269.04 0.0
269.6 0.0
270.12 0.0
272.5 0.0
273.05 0.0
273.61 0.0
274.13 0.0
274.69 0.0
275.12 0.1
275.69 0.0
276.21 0.0
276.77 0.0
277.29 0.0
277.85 0.0
278.37 0.0
278.92 0.0
279.45 0.0
283.99 1.1
284.59 0.0
285.12 0.0
285.87 0.0
286.2 0.0
286.44 0.0
286.95 0.0
287.27 0.0
287.52 0.0
288.03 0.0
288.58 0.0
289.11 0.0
289.65 0.0
290.19 0.0
298.78 0.1
299.36 0.0
299.87 0.0
300.44 0.0
300.96 0.1

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
302.06 4.4
302.84 0.0
303.26 0.4
303.87 0.0
304.35 0.0
304.96 0.0
305.46 0.0
306.09 0.1
306.63 0.0
307.18 0.1
307.74 0.0
308.28 0.0
308.81 0.0
309.36 0.0
309.88 0.0
310.44 0.0
310.96 0.0
311.52 0.0
312.03 0.0
313.96 0.1
314.24 0.1
314.79 0.0
315.2 0.1
316.08 0.1
316.74 0.0
317.16 0.0
317.82 0.0
318.24 0.0
318.91 0.0
319.32 0.0
319.99 0.0
320.49 0.0
320.87 0.0
323.12 0.1
323.69 0.0
324.2 0.0
324.75 0.0
325.28 0.0
326.17 0.1
327.12 0.1
327.68 0.0
328.05 0.1
328.6 0.0
329.12 0.0
329.66 0.0
330.2 0.0
330.73 0.0
331.28 0.0
332.0 0.1
332.54 0.0
332.87 0.0
333.1 0.0
333.62 0.0
334.19 0.0
334.7 0.0
335.25 0.0
335.78 0.0

Annotations:

^{1,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_5--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
336.32 0.0

Annotations:

^{1,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_5--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
336.86 0.0
339.94 0.1
340.48 0.0
341.03 0.0
341.55 0.0
342.11 0.0

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
342.63 0.0
343.1 0.1
343.92 0.4
344.48 0.0
345.06 0.7

Annotations:

^{2,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_5--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
346.11 0.0
346.68 0.0
347.19 0.0
347.77 0.0
348.27 0.0
348.62 0.0
348.85 0.0
349.35 0.0
349.7 0.0
349.93 0.0
350.44 0.0
352.96 0.1
353.52 0.0
354.04 0.0
354.6 0.0
355.12 0.0
356.04 0.8
356.32 0.2
356.9 0.1
357.46 0.0
358.0 0.0
358.54 0.0
359.08 0.0
359.62 0.0
360.15 0.0
361.03 0.6

Annotations:

^{0,2}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_2--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
361.59 0.0
362.06 0.1
362.62 0.0
363.23 0.0
363.69 0.0
364.32 0.0
364.76 0.0
365.4 0.0
366.0 0.2
366.27 0.1
366.98 0.1
367.54 0.0
368.1 0.0
368.62 0.0
369.17 0.0
369.7 0.0
370.23 0.0
370.78 0.0
371.3 0.0
371.97 0.1

Annotations:

^{1,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
372.64 0.1
373.2 0.1
373.81 0.1
374.32 0.1
374.87 0.0
375.43 0.0
376.11 0.2
376.69 0.0
377.2 0.0
377.76 0.0
378.28 0.0
378.83 0.0
379.36 0.0
379.83 0.2
380.37 0.0
380.94 0.0
381.45 0.0
381.94 0.1
382.48 0.0
383.03 0.0
383.55 0.0
384.11 0.0

Annotations:

redEnd--??1D-GalNAc,p--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
384.63 0.0

Annotations:

redEnd--??1D-GalNAc,p--3b1D-Gal,p--3?1S/#lcleavage$MONO,Und,-H,0,redEnd
385.19 0.0
385.93 0.0
386.48 0.0
387.03 0.0
387.77 0.1
388.3 0.0
388.86 0.0
389.38 0.0
389.71 0.0
390.09 0.1
390.65 0.0
391.19 0.0
391.72 0.0
392.06 0.1
392.61 0.0
393.29 0.0
393.86 0.0
394.38 0.0
394.94 0.0
395.46 0.0
396.02 0.0
396.54 0.0
397.1 0.0
397.62 0.0
401.73 0.1
402.34 0.1
402.92 0.1
404.06 1.8
404.99 0.3
405.55 0.0
406.09 0.0
406.63 0.0
407.16 0.0
407.71 0.0
408.24 0.0
408.79 0.0
409.31 0.0
409.85 0.0
411.21 0.0
411.78 0.0
412.3 0.0
412.86 0.0
413.37 0.0
413.94 0.0
414.45 0.0
415.02 0.0
415.53 0.0
416.16 0.1

Annotations:

^{1,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_5--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
416.75 0.0
417.22 0.1
417.78 0.0
418.31 0.0
419.1 0.2
419.78 0.1
420.05 0.1
420.47 0.1
421.13 0.2
421.9 0.4
422.15 0.9
422.43 0.5
422.83 0.1
423.16 0.2
423.72 0.0
424.24 0.0
424.8 0.0
425.32 0.0
425.88 0.0
426.39 0.0
426.95 0.0
427.47 0.0
428.09 0.1
428.43 0.1
428.97 0.1
429.53 0.0
430.06 0.0
430.61 0.0
431.13 0.0
431.69 0.0
432.21 0.0
432.77 0.0
433.29 0.0
435.32 0.1
435.87 0.0
436.44 0.0
436.95 0.0
437.77 0.1
438.35 0.0
438.87 0.0
439.41 0.0
439.95 0.0
440.48 0.0
441.03 0.0
441.55 0.0
442.11 0.0
442.62 0.0
446.04 0.0
446.61 0.0
447.14 0.0
447.69 0.0
448.21 0.0
448.77 0.0
449.29 0.0
449.85 0.0
450.37 0.0
464.09 10.1

Annotations:

redEnd--??1D-GalNAc,p--3b1D-Gal,p--3?1S$MONO,Und,-H,0,redEnd
465.11 1.4
465.74 0.0
466.34 0.0
466.81 0.0
467.42 0.0
467.94 0.0
468.49 0.0
469.02 0.0
469.57 0.0

There are 37 similar spectra:

Id Structure Score

1.00

6442

0.97

6503

0.97

6511

0.97

6519

0.97

6577

0.97

0.97

4830

0.96

0.96

3490

0.96

6691

0.96

0.96

6696

0.95

5410

0.95

7397

0.89

7426

0.89

7619

0.88

6504

0.85

6512

0.85

6520

0.85

6578

0.85

6649

0.83

0.83

3489

0.82

6690

0.82

0.82

0.80

7679

0.77

7686

0.77

0.77

7971

0.73

7161

0.65

5537

0.53

7398

0.51

7427

0.51

5386

0.51

0.51

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 463.12
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

Report errors in this entry

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