Structure

    redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

200.0400.0600.0800.01000m/z0.02.0e+24.0e+2Abundance
Peak Intensity
291.1 1.5
309.0 2.6
324.04 1.7
346.03 1.6

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
348.02 17.3

Annotations:

B ?1HexNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
366.05 27.5

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
366.32 4.5
367.06 1.9
369.1 2.1
384.07 67.0

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
384.43 3.1
385.06 9.9
387.12 2.1

Annotations:

BZ b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
405.1 14.0

Annotations:

BY b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
406.09 2.6
455.14 1.5
461.05 9.5
462.12 2.1
479.09 5.1
479.32 2.0
480.04 2.1
491.1 2.3
492.09 5.4
509.04 2.1
521.16 4.7
522.1 3.2
527.12 10.9
529.12 1.8
533.16 3.5
534.13 1.8
550.1 2.4
551.16 511.4

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
552.13 84.9
552.78 4.3
569.16 30.3

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
570.27 1.9
587.19 57.1

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.18 15.4
588.73 3.4
593.15 1.5
607.34 1.6
625.24 20.5
625.68 1.6
626.17 3.2
637.22 39.6
638.16 5.7
638.56 1.8
646.16 1.6
665.17 2.5
683.04 1.6
685.09 1.7
695.07 4.0
712.15 1.9
713.19 59.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
714.19 9.2
730.32 1.8
731.19 1.9

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
732.12 2.0
754.24 15.5
755.12 3.3
756.23 2.7
772.39 10.0

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
773.32 2.2
782.55 3.6
786.22 4.5
787.29 3.4
790.23 16.6

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.26 11.9
792.17 2.9
795.02 1.5
807.31 1.7
817.19 2.9
821.53 1.7
828.28 36.6
829.24 17.4
831.23 9.0
832.21 4.7
835.23 2.4
839.23 1.9
846.24 4.1
847.22 1.8
856.3 1.8
858.1 2.2
858.96 1.7
859.31 2.1
862.12 3.6
874.97 2.5
875.32 2.9
876.28 114.1
876.7 7.2
877.3 48.4
887.33 1.7
888.19 1.6
891.19 2.9
894.26 22.6
895.32 7.5
899.24 10.0
900.23 4.8
901.1 6.5
905.34 2.0

There are 11 similar spectra:

Id Structure Score

1.00

8008

0.99

0.99

8006

0.95

0.95

4866

0.94

0.94

5726

0.94

5439

0.94

6810

0.93

7173

0.55

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 935.38
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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