Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p$MONO,Und,-H,0,redEnd

Rainbow trout mucus O-glycosylation

GlyTouCan Accession Number: Loading...

300.0400.0500.0600.0700.0800.0900.0m/z0.020406080Abundance
Peak Intensity
279.12 0.2
280.2 0.5
287.17 0.4
291.23 0.3
300.37 0.3
309.03 0.3
340.23 0.4
346.19 0.3

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
347.36 0.7

Annotations:

B ?1D-Gal,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
348.18 0.7

Annotations:

B ?1D-Gal,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
348.44 0.3

Annotations:

B ?1D-Gal,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
351.25 0.4
364.1 1.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
383.85 0.5

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
384.25 8.7

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
384.67 0.4

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
385.23 0.3
387.21 0.6
387.55 0.3
388.04 0.5
390.22 0.7
407.05 0.4

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
407.39 0.5

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
408.07 0.5

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
408.38 1.3
425.0 1.4

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
425.41 3.1

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
459.34 0.7
468.45 0.3
479.37 1.7
479.66 0.4
499.27 0.5
501.45 0.4
502.19 0.2
509.25 0.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
510.06 0.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
519.21 0.3
519.9 0.3
520.2 0.3
521.36 4.3
522.25 0.9
526.78 1.1
527.59 5.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
528.5 0.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
549.63 0.4
550.27 0.5

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
551.3 39.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
552.31 4.0
553.31 0.5
568.05 0.3
569.45 2.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
569.91 0.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
570.36 1.3
580.47 0.9
587.34 72.2

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
587.97 2.1

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
588.43 6.9
593.34 0.4
611.53 0.3
622.49 1.2
623.66 0.4
664.34 6.5
664.74 0.3
665.08 0.5
665.55 0.9
666.4 1.0
671.47 0.3
674.72 0.3
675.46 0.5
676.4 1.0
680.29 0.6
682.32 6.1
683.39 1.0
707.38 0.3
712.54 0.3
713.58 1.4
724.35 13.1
725.22 3.5
725.53 2.3
725.74 0.6
754.07 0.6
754.55 1.1
755.35 0.8
759.21 0.4
772.51 2.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
773.15 1.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
773.82 0.3
790.64 1.0

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
791.41 1.4
791.78 1.0
833.46 0.5
858.75 0.3
876.15 1.2
876.78 1.8
877.25 1.0
877.77 0.5
891.97 0.3
894.45 1.6
894.68 1.2
899.08 0.4

There are 21 similar spectra:

Id Structure Score

5440

0.96

4867

0.90

0.90

5727

0.90

5441

0.87

6811

0.86

7150

0.86

4809

0.85

0.85

5732

0.85

7174

0.85

5728

0.84

6812

0.76

5442

0.76

4810

0.75

0.75

5730

0.72

8008

0.57

0.57

8007

0.55

0.53

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 935.38
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • 78 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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