Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
209.94 4.1
215.97 7.0
217.96 40.6
219.96 4.6

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
222.02 9.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
225.94 4.6
229.99 10.3
234.0 5.7
235.96 29.6
262.02 7.0

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
274.01 6.1

Annotations:

Z^{0,2}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
287.99 60.7

Annotations:

^{0,2}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_2)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
288.41 5.8
288.97 5.1
290.05 13.9

Annotations:

Z^{2,5}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
292.01 11.0

Annotations:

Y^{0,2}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
297.04 4.6
303.98 7.0

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd ^{2,5}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_5)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd Z^{0,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
305.03 6.9

Annotations:

Z^{0,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd ^{0,2}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_2)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
306.02 2133.5

Annotations:

^{0,2}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_2)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_1_3)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
306.55 90.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_1_3)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
307.0 221.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_1_3)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
307.56 8.2

Annotations:

Y^{2,5}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
308.02 13.8

Annotations:

Y^{2,5}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
317.08 7.4

Annotations:

^{0,3}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_3)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
322.01 5.5

Annotations:

^{2,5}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_5)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd Y^{0,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
324.02 51.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_1_3)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
325.06 4.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_1_3)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
347.13 4.2

Annotations:

^{0,4}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_4)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_4)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
352.04 7.3

Annotations:

^{3,5}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_3_5)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
407.11 59.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
408.09 8.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
417.06 22.3
423.89 12.6
425.13 135.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.67 5.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
426.1 26.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
434.03 4.7
435.1 9.2
440.04 7.0
445.12 4.9
449.11 5.8
451.13 5.8
467.09 99.7

Annotations:

Z^{1,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd
467.59 5.2

Annotations:

Z^{1,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd
468.16 21.4
475.09 20.6
476.14 4.3
477.12 64.1
478.07 14.4
485.14 24.5

Annotations:

Y^{1,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd
493.12 355.0
494.1 61.4
495.12 339.6

Annotations:

^{0,2}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
496.09 64.7

Annotations:

^{0,2}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
509.09 9.5
510.09 14.0
511.13 104.1

Annotations:

^{2,5}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
512.15 30.5

Annotations:

^{2,5}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
513.16 129.1
514.09 16.6
518.14 27.3
519.28 4.7
529.12 55.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
530.12 32.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
531.12 7.3
548.15 12.8
549.15 4.0
566.14 5.6
594.17 8.4
606.1 12.4
612.18 5.6

Annotations:

^{0,4}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd ^{0,2}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_2)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
620.19 16.0
621.13 4.2
624.18 33.2
625.14 9.8
638.19 190.2
639.16 55.0
644.94 5.3
654.18 31.3
655.18 6.0
656.21 49.9
657.2 15.6
670.11 28.7
671.18 14.3
672.1 11.5

Annotations:

^{0,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_4)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_4)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
673.22 7.0

Annotations:

^{0,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_4)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_4)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
684.19 7.1

Annotations:

^{1,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_5(--3b1D-GlcNAc,p)--6a2D-NeuGc,p$MONO,Und,-H,0,redEnd
686.88 6.7
688.06 72.7

Annotations:

^{1,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd
688.99 40.9

Annotations:

^{1,3}X_{NeuGc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6a2D-NeuGc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd
690.22 5.5
695.15 4.5
696.2 113.2
697.18 39.7
698.15 4.5
701.15 8.2
702.22 867.8
703.19 162.8
734.23 11.0

There are 14 similar spectra:

Id Structure Score

5706

0.91

6714

0.91

5425

0.87

3751

0.87

6801

0.86

7989

0.86

4846

0.85

0.85

5707

0.85

0.84

6715

0.84

7403

0.63

7432

0.63

7145

0.61

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 731.28
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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