Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd

Rainbow trout mucus O-glycosylation

GlyTouCan Accession Number: Loading...

Peak Intensity
167.99 2.6
168.54 0.0
186.07 0.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
186.62 0.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
193.17 0.3
193.72 0.0
202.01 5.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
202.67 0.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
204.22 1.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
204.97 0.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
205.53 0.0
219.89 1.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
220.51 0.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p$MONO,Und,-H,0,redEnd
252.31 0.6
252.86 0.0
256.51 1.1
257.05 0.0
263.78 1.2
264.35 0.0
284.21 0.4
284.77 0.0
294.83 0.8
295.38 0.0
308.01 1.6
308.56 0.0
312.28 2.0
312.93 0.0
317.3 0.7
317.85 0.0
319.05 1.4
319.61 0.0
329.06 1.2
329.61 0.0
343.66 0.9
344.21 0.0
346.97 1.2
347.37 2.1
347.94 0.0
354.84 1.1
355.24 0.8
355.79 0.0
358.06 0.5
358.62 0.0
359.04 0.6
359.61 0.0
364.39 0.7
364.91 0.5
365.41 1.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
366.1 0.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
366.38 0.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
366.93 0.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
368.97 1.3
369.52 0.0
370.8 0.3
371.36 0.0
380.15 0.6
380.99 0.5
381.53 0.0
384.16 1.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
384.7 0.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
388.93 2.0
389.48 0.0
391.25 0.2
407.25 108.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
408.29 12.0
408.94 0.0
425.28 0.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
426.28 1.6
426.92 0.0
436.68 1.1
437.25 0.0
443.84 0.4
444.39 0.0
452.91 0.4
453.46 0.0
479.31 1.3
479.86 0.0
499.09 2.6
499.64 0.0
501.28 1.3
501.85 0.0
506.55 1.6
507.11 0.0
512.19 1.9
512.75 0.0
525.79 0.9
526.43 0.5
527.5 7.9
528.23 1.3
528.63 0.4
529.19 0.0
543.27 0.9
544.11 0.2
544.88 0.4
545.53 1.8
546.01 0.9
546.55 0.0
550.98 2.0
551.53 0.0
561.26 0.3

There are 36 similar spectra:

Id Structure Score

5546

1.00

3868

0.99

3110

0.99

6699

0.99

7976

0.99

5934

0.99

7728

0.99

0.99

5415

0.99

6795

0.99

4259

0.99

5693

0.98

4833

0.98

0.98

3998

0.98

4077

0.98

7163

0.98

5548

0.96

5507

0.93

5416

0.89

6700

0.84

4800

0.82

0.82

0.78

7680

0.78

7687

0.78

5694

0.71

5935

0.70

6701

0.63

4231

0.61

5223

0.61

3743

0.61

6796

0.58

4229

0.57

5221

0.57

5768

0.51

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 586.24
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • 78 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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