Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

200.0400.0600.0800.01000m/z0.01.0e+42.0e+43.0e+44.0e+45.0e+4Abundance
Peak Intensity
287.98 6.5
290.01 429.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.96 12.9
306.02 2.0
308.0 26.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
360.57 1.7
366.06 8.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
380.02 2.1
384.08 42.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
385.04 3.9
417.12 4.0
426.21 2.5
435.06 4.8
436.19 3.3

Annotations:

Z^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
451.13 4.8
454.07 73.6

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
469.16 2.6
470.15 3.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
477.11 36.5
478.11 6.3
493.08 4.4
493.51 2.6
494.12 6.0
495.12 23.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
501.24 1.7
507.21 4.0
513.14 32.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
514.09 17.1
514.34 4.0
514.76 1.7
519.06 2.6
537.15 23.8
555.31 1.8
563.16 6.8
567.18 10.5
579.15 6.0
579.9 2.2
580.16 3.0
581.12 135.8
581.62 2.7
582.12 24.7
597.14 97.6
598.08 6.7
613.15 6.8
615.16 135.1

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
615.73 4.5
616.1 4.3
616.46 2.0
631.24 16.0
632.2 2.3
639.1 7.9
641.01 1.9
653.29 2.1
655.14 4.2
655.52 1.9
656.15 17.1
657.18 1442.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
658.16 66.8
658.81 2.3
673.18 120.6
674.25 237.0
675.19 45552.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
676.13 2469.0
677.15 129.8
678.18 10.1
678.65 2.0
701.21 5.5
727.17 5.5
745.13 8.4

Annotations:

^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
775.78 2.4
804.22 2.0
813.68 3.1
816.23 4.4
828.11 5.8
829.25 2.5
838.11 2.3
840.15 2.4
841.08 1.7
844.25 5.4
858.79 2.9
859.07 2.4
870.27 6.7
888.28 13.0
900.12 7.6
904.26 40.7
904.69 1.9
905.15 8.2
906.23 64.7
906.8 2.0
907.32 2.9
912.18 3.4
921.3 10.9
922.28 1265.7
923.25 117.4
923.8 2.4
924.23 3.6
930.25 123.0
931.22 12.9
931.91 4.4
967.21 2.8

There are 41 similar spectra:

Id Structure Score

1.00

1.00

1.00

5207

1.00

7629

1.00

4083

1.00

5443

1.00

5398

1.00

1.00

5735

1.00

4245

1.00

5237

1.00

4812

1.00

1.00

3505

1.00

5521

1.00

7238

1.00

6592

1.00

1.00

5796

1.00

6814

1.00

3763

1.00

7394

1.00

7423

1.00

7175

1.00

7184

1.00

7151

1.00

5177

1.00

5183

1.00

4208

1.00

7696

0.99

0.99

7684

0.99

7691

0.99

0.99

3977

0.97

5189

0.97

7628

0.96

8014

0.94

8013

0.94

7153

0.59

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 965.35
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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