Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
271.96 2.6
275.95 0.8
289.98 95.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.54 1.9
290.92 5.1
291.77 0.6
299.07 0.5
299.9 2.4
301.16 2.0
308.02 1.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
334.0 1.3
348.01 2.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.09 1.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
384.96 1.1
389.03 1.0
407.14 3.3
408.1 1.4
434.99 1.4
435.33 0.6
451.17 2.7
466.13 0.8
469.3 0.9
477.06 21.1
477.58 1.6
478.15 2.7
479.15 3.4
488.98 0.5
492.67 1.7
493.07 1.6
495.11 2.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
500.13 1.0
509.07 2.3
513.09 4.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
514.2 0.6
514.57 2.1
531.08 1.3
534.09 1.5
550.96 2.2
553.96 0.7
569.18 8.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
587.18 21.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.2 7.8
601.08 1.0
613.21 0.5
620.2 1.3
621.27 0.5
629.09 1.2
630.18 2.1
638.18 8.2
639.15 1.4
640.29 1.4
644.29 0.9
656.02 1.4
657.18 24.6

Annotations:

^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
657.7 1.8
658.11 10.7
659.23 0.7
666.97 1.9
669.72 0.7
674.87 5.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
675.12 0.9
680.13 17.3
687.14 1.1
692.09 0.8
694.87 1.0
698.81 1.7
699.13 4.1
703.21 0.7
710.22 1.2
711.23 2.6
715.58 4.0
716.22 3.2
717.22 8.5
717.83 0.6
720.25 1.7
728.01 1.9
732.13 1.1
733.02 0.8
740.12 0.6
740.53 1.5
742.82 0.6
753.25 1.0
768.96 0.9
770.07 1.1
771.16 1.6
782.21 1.7
798.54 0.7
798.81 0.9
800.21 48.8
801.22 6.8
806.19 1.1
818.19 80.5
834.19 0.6
835.21 3.7
842.37 5.3
842.98 5.0

There are 38 similar spectra:

Id Structure Score

5722

0.95

5721

0.94

4808

0.93

0.93

5436

0.92

7409

0.90

7438

0.90

4858

0.84

0.84

5435

0.82

5520

0.80

6806

0.78

7148

0.72

5570

0.71

8003

0.69

4240

0.69

5232

0.69

4241

0.67

5233

0.67

6807

0.65

4239

0.64

5231

0.64

4082

0.63

6734

0.63

5437

0.63

4860

0.63

0.63

5785

0.62

5394

0.62

0.62

3500

0.61

8002

0.59

5786

0.57

5571

0.56

3880

0.54

3974

0.53

4859

0.53

0.53

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 877.33
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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